Step 1: Heat the Oven and Prep the Baking Dish - Set your oven to 400°F so it is hot and ready when the pork chops are finished browning. Lightly coat an 8 by 8 inch baking dish with nonstick cooking spray, then set it near the stove. Keeping the baking dish close makes the transfer easy once the pork chops come out of the skillet, and it keeps you from juggling hot pans while dinner is moving along.
Step 2: Sear the Pork Chops - Warm the olive oil in a large skillet over medium high heat. Once the oil is shimmering, add the pork chops in a single layer. Let them cook for about 2 to 3 minutes on the first side, then turn them over and cook for another 2 to 3 minutes. You are not trying to cook the pork all the way through here. This quick sear gives the outside a little color and builds that deeper savory flavor that makes a simple baked pork chop taste special. Move the browned pork chops into your prepared baking dish, arranging them in one even layer.
Step 3: Whisk Together the Maple Dijon Sauce - In a medium bowl, whisk together the maple syrup, Dijon mustard, apple cider vinegar, minced garlic, garlic salt, onion powder, and red pepper flakes. Give it a good stir until the mustard is fully blended into the maple syrup and the sauce looks smooth. Take a second to smell it before you pour it over the pork. It has that sweet maple scent first, then the sharp mustard and garlic come through behind it. This sauce is doing most of the heavy lifting in the recipe, so make sure every bit gets mixed together well.
Step 4: Coat the Pork in Sauce - Pour the maple Dijon sauce all over the seared pork chops. Use a spoon to nudge some sauce over the tops if needed, making sure each chop gets a good coating. The pork will finish cooking in the sauce, and the juices from the meat will mingle with the maple and mustard as everything bakes. Do not worry if the sauce looks loose at this point. It will reduce slightly in the oven and become richer around the edges of the dish. That is exactly what you want, especially if mashed potatoes are waiting nearby.
Step 5: Bake Until Tender and Juicy - Bake the pork chops uncovered for about 18 minutes, or until the thickest part of each chop reaches 145°F on an instant read thermometer. Pork chops can go from juicy to dry quickly, so a thermometer is your best friend here. Once they reach temperature, pull the dish from the oven and let the pork chops rest for a few minutes. This gives the juices time to settle back into the meat instead of running out onto the plate. The result is pork that cuts easily with a fork and stays tender all the way through.
Step 6: Spoon Over the Pan Sauce - Right before serving, spoon the warm maple Dijon sauce from the baking dish over each pork chop. Be generous with it. That sauce has picked up all the savory goodness from the pork, and it is too good to leave behind. Set the pork chops on a plate with your favorite sides, then drizzle a little extra sauce over the potatoes or vegetables. This is the moment when a simple weeknight dinner starts feeling like something people will remember.